| 英文名 |
acetylenecarboxylate hydratase |
| Example Structure |
 |
| 别名 |
acetylenemonocarboxylic acid hydrase, dehydratase, malonate semialdehyde, EC 4.2.1.71, malonate semialdehyde dehydratase, malonate semialdehyde dehydratase, malonate semialdehyde, malonate-semialdehyde dehydratase |
| EC Number |
4.2.1.27 |
| CAS编号 |
9024-26-4 |
| Comments |
The reaction is effectively irreversible, favouring oxopropanoate (malonic semialdehyde) and its tautomers. Also acts on 3-butynoate forming acetoacetate. The mechanism appears to involve hydration of the acetylene to 3-hydroxypropenoate, which will spontaneously tautomerize to 3-oxopropanoate. It is thus analogous to EC?4.1.1.78, acetylenedicarboxylate decarboxylase, in its mechanism. |
| Cofactor |
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| History |
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| Reactions |
3-oxopropanoate = propynoate + H(2)O. |
