| 英文名 |
(E)-2-methylbutanal oxime monooxygenase |
| Example Structure |
 |
| 别名 |
CYP71E7 |
| EC Number |
1.14.14.41 |
| CAS编号 |
|
| Comments |
This cytochrome P-450 (heme thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucosides lotaustralin and linamarin. It catalyses three different activities – isomerization of its substrate the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation. |
| Cofactor |
|
| History |
|
| Reactions |
(1) (E)-2-methylbutanal oxime + [reduced NADPH–hemoprotein reductase] + O(2) = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH–hemoprotein reductase] + 2 H(2)O. (2) (E)-2-methylpropanal oxime + [reduced NADPH–hemoprotein reductase] + O(2) = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH–hemoprotein reductase] + 2 H(2)O. |
