| 英文名 |
glucosinolate gamma-glutamyl hydrolase |
| Example Structure |
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| 别名 |
At4g30530, gamma-glutamyl peptidase 1, gamma-glutamyl peptidase 3, GGP1, GGP3 |
| EC Number |
3.4.19.16 |
| CAS编号 |
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| Comments |
This enzyme, characterized from the plant?Arabidopsis thaliana, participates in the biosynthesis of the plant defense compounds glucosinolates and camalexin. It is the only known plant enzyme capable of hydrolysing the ¦Ã-glutamyl residue of glutathione in the cytosol. |
| Cofactor |
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| History |
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| Reactions |
(1) An S-((1E)-1-(hydroxyimino)-omega-(methylsulfanyl)alkyl)-L- glutathione + H(2)O = an S-((1E)-1-(hydroxyimino)-omega- (methylsulfanyl)alkyl)-L-cysteinylglycine + L-glutamate. (2) (E)-1-(glutathion-S-yl)-2-(1H-indol-3-yl)acetohydroximate + H(2)O = (E)-1-(glycylcystein-S-yl)-2-(1H-indol-3-yl)acetohydroximate + L-glutamate. (3) 2-(glutathion-S-yl)-2-(1H-indol-3-yl)acetonitrile + H(2)O = 2-(glycylcystein-S-yl)-2-(1H-indol-3-yl)acetonitrile + L-glutamate. (4) (Z)-1-(glutathion-S-yl)-2-phenylacetohydroximate + H(2)O = (Z)-1- (glycylcystein-S-yl)-2-phenylacetohydroximate + L-glutamate. |