| 英文名 |
phenylacetone monooxygenase |
| Example Structure |
 |
| 别名 |
4-hydroxyacetophenone monooxygenase, Baeyer-Villiger monooxygenase, BVMO, EtaA, HAPMO, M-PAMO, More, PAMO, phenylacetone monooxygenase |
| EC Number |
1.14.13.92 |
| CAS编号 |
|
| Comments |
A flavoprotein (FAD). NADH cannot replace NADPH as coenzyme. In addition to phenylacetone, which is the best substrate found to date, this Baeyer-Villiger monooxygenase can oxidize other aromatic ketones [1-(4-hydroxyphenyl)propan-2-one, 1-(4-hydroxyphenyl)propan-2-one and 3-phenylbutan-2-one], some alipatic ketones (e.g. dodecan-2-one) and sulfides (e.g. 1-methyl-4-(methylsulfanyl)benzene). |
| Cofactor |
FAD |
| History |
|
| Reactions |
Phenylacetone + Nadph + O(2) = benzyl acetate + NADP(+) + H(2)O. |