SilanediaMide, N,N,N’,N’-tetraethyl CAS#: 27804-64-4; 凯望编码 (ChemWhat Code): 282765
Identification
| 英文名 | Bis(diethylamino)dihydrosilane |
| 分子结构 |  |
| CAS编号 | 27804-64-4 |
| MDL Number | MFCD19105220 |
| 别名 | bis(diethylamino)silane 27804-64-4 Silanediamine, N,N,N’,N’-tetraethyl- MFCD19105220 SCHEMBL35573 DTXSID401301011 N,N,N’,N’-Tetraethylsilanediamine BCP30198 SilanediaMide, N,N,N’,N’-tetraethyl Bis(diethylamino)silane, 99% (99.999%-Si) BDEAS PURATREM |
| 分子式 | C8H22N2Si |
| 分子量 | 174.359 |
| InChI | InChI=1S/C8H20N2Si/c1-5-9(6-2)11-10(7-3)8-4/h5-8H2,1-4H3 |
| InChI Key | MVYGKQJKGZHAAI-UHFFFAOYSA-N C8H20N2Si/c1-5-9(6-2)11-10(7-3)8-4/h5-8H2,1-4H3 |
| Isomeric SMILES | CCN(CC)[Si]N(CC)CC |
Physical Data
| Appearance | Transparent liquid |
| Boiling Point, °C | Pressure (Boiling Point), Torr |
| 70 | 15 |
Spectra
| Description (NMR Spectroscopy) | Nucleus (NMR Spectroscopy) | Solvents (NMR Spectroscopy) |
| Chemical shifts | 1H | chloroform-d1 |
| Description (IR Spectroscopy) | Solvent (IR Spectroscopy) | Temperature (IR Spectroscopy), °C |
| Bands | gas | 2971 – 790 cm**(-1) |
Route of Synthesis (ROS)
Route of Synthesis (ROS) of Bis(diethylamino)dihydrosilane CAS: 27804-64-4
| Conditions | Yield |
| diethylamine With n-butyllithium In hexane at -60℃; for 15h; Inert atmosphere; Large scale; With Dichlorosilane In hexane at -60℃; for 15h; Temperature; Inert atmosphere; Large scale; Experimental Procedure Under a nitrogen atmosphere, was added 5000ml of n-butyllithium in n-hexane in the reaction vessel, at a concentration of 2.5 moles per liter. Under stirring, 1000 g of diethylamine was added dropwise to the reaction kettle to control the dropping rate to prevent the temperature of the system from being kept at -60 ° C. After the dropping was completed, the temperature inside the kettle was kept at -60 And the mixture was stirred for 15 hours. Then pass into dichlorosilane 690 grams, control passed into the kettle to maintain a speed of -60 , and finally stirred at -60 after 15 hours, warmed to room temperature. Hexane solvent was distilled off at atmospheric pressure and then vacuum distilled bis (diethylamino) silane, distillation pressure 15mmHg, distillation temperature of 70 . To give product 990 g, yield (with respect to the weight of silicon molar ratio) was 91.1%. | 91.1% |
| With ethylene bis(tetrahydroindenyl)titanium dichloride; 4-fluoro-benzamidoxime; zinc 2-ethylhexanoate; Dichlorosilane; copper(II) nitrate; lithium tetraphenylborate tris(1,2-dimethoxyethane) In hexane; water at 60 – 120℃; for 5h; Temperature; Reagent/catalyst; Inert atmosphere; | 89% |
| With Dichlorosilane In hexane at -25℃; for 3h; Inert atmosphere; | 75% |
Safety and Hazards
No data available
Other Data
| Transportation | Under the room temperature and away from light |
| Storage | Under the room temperature and away from light |
| Shelf Life | 1 year |
| Market Price |
| Druglikeness | |
| Lipinski rules component | |
| 分子量 | 174.362 |
| logP | 1.88247 |
| HBA | 2 |
| HBD | 0 |
| Matching Lipinski Rules | 4 |
| Veber rules component | |
| Polar Surface Area (PSA) | 6.48 |
| Rotatable Bond (RotB) | 6 |
| Matching Veber Rules | 2 |
| Use Pattern |
| Silanediamide-nnnn-tetraethyl CAS#: 27804-64-4 be used as an interface modifier in ceramics and glass production, improving surface properties. |
试剂采购 | |
| 没有试剂厂商? | 向凯望发送快速询价 |
| 想要被列为试剂厂商? (付费服务) | 点击这里联系凯望 |
认证生产商 | |
| Warshel Chemical Ltd | http://www.warshel.com/ |
| 想要被列为认证生产商 (需要通过认证)? | 请下载并填写 这份表格并发邮件到approved-manufacturers@chemwhat.com |
其他供应商 | |
| Watson International Limited | 访问Watson官网 |
如需其他帮助，请联系我们 | |
| 联系我们获取其它信息或服务 | 点击这里联系凯望 |