| 英文名 |
sn-1 linoleoyl-lipid 6-desaturase |
| Example Structure |
 |
| 别名 |
DELTA6 desaturase, DELTA6-acyl-lipid desaturase, DELTA6-desaturase, desD |
| EC Number |
1.14.19.46 |
| CAS编号 |
|
| Comments |
The enzyme, characterized from cyanobacteria, introduces a cis double bond at carbon 6 of linoleoyl groups (18:2) attached to the sn-1 position of glycerolipids. The enzyme is a front-end desaturase, introducing the new double bond between a pre-existing double bond and the carboxyl-end of the fatty acid. It is nonspecific with respect to the polar head group of the glycerolipid. |
| Cofactor |
|
| History |
|
| Reactions |
A 1-linoleoyl-2-acyl-[glycerolipid] + 2 reduced ferredoxin [iron-sulfur] cluster + O(2) + 2 H(+) = a 1-gamma-linolenoyl-2-acyl-[glycerolipid] + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H(2)O. |