Sodium bis(fluorosulfonyl)imide CAS#: 100669-96-3; 凯望编码 (ChemWhat Code): 1499430

IdentificationPhysical DataSpectra
Route of Synthesis (ROS)Safety and HazardsOther Data

Identification

Product NameSodium bis(fluorosulfonyl)imide
IUPAC Namesodium bis(fluorosulfonyl)azanide
Molecular StructureStructure of Sodium bis(fluorosulfonyl)imide CAS 100669-96-3
CAS Registry Number 100669-96-3
EINECS NumberNo data available
MDL NumberNo data available
Beilstein Registry NumberNo data available
SynonymsNaFSI
Molecular FormulaF2NNaO4S2
Molecular Weight203.109
InChIInChI=1S/F2NO4S2.Na/c1-8(4,5)3-9(2,6)7;/q-1;+1
InChI KeyVCCATSJUUVERFU-UHFFFAOYSA-N
Canonical SMILESO=S(=O)(F)[N-]S(=O)(=O)F.[Na+]
Patent Information
No data available

Physical Data

AppearanceWhite crystalline powder
SolubilityH2O: Soluble (5%), clear, colorless.
Flash PointNo data available
Refractive indexNo data available
SensitivityHygroscopic

Spectra

No data available

Route of Synthesis (ROS)

No data available

Safety and Hazards

Pictogram(s)corrosionskullexclamation-mark
SignalDanger
GHS Hazard StatementsH301 (33.3%): Toxic if swallowed [Danger Acute toxicity, oral]
H302 (33.3%): Harmful if swallowed [Warning Acute toxicity, oral]
H314 (66.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
H318 (66.7%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
H335 (33.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
Information may vary between notifications depending on impurities, additives, and other factors.
Precautionary Statement CodesP260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P403+P233, P405, and P501
(The corresponding statement to each P-code can be found at the GHS Classification page.)

Other Data

TransportationNONH for all modes of transport
Under the room temperature and away from light
HS CodeNo data available
StorageUnder the room temperature and away from light
Shelf Life2 years
Market PriceUSD
Druglikeness
No data available
Use Pattern
Research on Electrolytes for Lithium and Sodium Batteries
NaPF₆ serves as an electrolyte salt for Sodium-ion Batteries (SIBs) and acts as a supporting electrolyte in electrochemical research. For instance, it is soluble in carbonate-based solvent systems such as EC/DEC, PC, and DMC. Due to the superior electrochemical stability and high ionic conductivity of the PF₆⁻ anion, NaPF₆ is frequently utilized in the development of laboratory-scale battery systems.
Anion Exchange Agents in Organic Synthesis
As PF₆⁻ is classified as a weakly coordinating anion, NaPF₆ is commonly employed to: convert halide salts into hexafluorophosphate salts, synthesize quaternary ammonium PF₆ salts, prepare ionic liquids, and facilitate anion exchange in metal complexes.
Supporting Electrolytes in Electrochemistry
It functions as a conductive salt in various electrochemical applications, including cyclic voltammetry (CV), electrodeposition, supercapacitors, and electrocatalysis research.
Functional Materials and Coordination Chemistry
It is utilized in the construction of PF₆⁻ coordination systems within the fields of metal-organic frameworks (MOFs), coordination chemistry, OLED materials, and luminescent materials.
Intermediates for Ionic Liquids
Many PF₆-based ionic liquids are synthesized via anion exchange reactions utilizing NaPF₆.

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